Publication Date: 2005-Mar-30
The IP.com Prior Art Database
Pesticidal mixtures of quinolines and cinnolines with other fungicides and pesticides are disclosed. Fungicidal compounds are often applied in conjunction with one or more other fungicides to control a wider variety of undesirable diseases and with other pesticides in order to control numerous pests within the same application. Typical pesticides include insecticides, nematocides, miticides, arthropodicides, bactericides or combinations thereof.
Quinoline and cinnoline fungicides such as Quinoxyfen are reported in U.S. 5,145,843 and are described by the following formula:
wherein X is CR5 or N, where R5 is H, Cl or CH3; Y is CR5’ where R5’ is H, Cl or Br;
z is O, S, SO, SO2, NR6, where R6 is H, alkyl, or acyl, or CR7R8, where R7 and R8 are independently H, acyl, alkyl, alkenyl, alkynyl, CN, or OH, or R7 and R8 combine to form a carbocyclic ring containing four to six carbon atoms; R1 to R4 are independently H, OH, NO2, Halo, alkyl, branched alkyl, alkoxy, halo, alkyl, halo alkoxy or halo alkylthio; or R1 and R2 or R2 and R3 combine to form a carbocyclic ring containing 4 to 6 carbon atoms; A is C1-C18 hydrocarbon, straight or branched, unsaturated or saturated, optionally including a hetero atom of O, S, SO or SO2; and optionally substituted with halo, halo alkoxy, hydroxy or acyl; cycloalkyl or cycloalkenyl; a phenyl group optionally substituted with H, CN, NO2, OH, halo, alkyl, acyl, haloalkyl, hydroxyalkyl, alkoxy, haloalkoxy, alkylthio, haloalkylthio, phenyl, substituted phenyl, phenoxy, substituted phenoxy, optionally substituted phenylthio, optionally substituted phenylalkyl, optionally substituted benzoyl and the like; a furyl group, a thienyl group and others as described in U.S. 5,145,843 and agronomically acceptable enantiomorphs, acid addition salts and metal complexes thereof.
Quinoline and cinnoline compounds can also be combined with other fungicides to form fungicidal mixtures and synergistic mixtures thereof. Fungicidal compounds are often applied in conjunction with one or more other fungicides to control a wider variety of undesirable diseases. When used in conjunction with other fungicide(s), quinoline and cinnoline fungicides can be formulated with the other fungicide(s), tank mixed with the other fungicide(s) or applied sequentially with the other fungicide(s). Such other fungicides include enestrobin, antimycin, SYP-048, IK-1140, NC-224, 2-(thiocyanatomethylthio)-benzothiazole, 2-phenylphenol, 8-hydroxyquinoline sulfate, Ampelomyces quisqualis, azaconazole, azoxystrobin, Bacillus subtilis, benalaxyl, benomyl, benthiavalicarb-isopropyl, benzylaminobenzene-sulfonate (BABS) salt, bicarbonates, biphenyl, bismerthiazol, bitertanol, blasticidin-S, borax, Bordeaux mixture, boscalid, bromuconazole, bupirimate, calcium polysulfide, captafol, captan, carbendazim, carboxin, carpropamid, carvone, chinomethionate, chloroneb, chlorothalonil, chlozolinate, Coniothyrium minitans, copper hydroxide, copper octanoate, copper oxychloride, copper sulfate, copper sulfate (tribasic), cuprous oxide, cyazofamid, cyflufenamid, cymoxanil, cyproconazole, cyprodinil, dazomet, debacarb, diammonium ethylenebis-(dithiocarbamate), dichlofluanid, dichlorophen, diclocymet, diclomezine, dichloran, diethofencarb, difenoconazole, difenzoquat ion, diflumetorim, dimethomorph, dimoxystrobin, diniconazole,diniconazole-M,dinobuton, dinocap,diphenylamine,dithianon, dodemor...