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Fungicidal Mixtures

IP.com Disclosure Number: IPCOM000116332D
Publication Date: 2005-Mar-30
Document File: 7 page(s) / 53K

Publishing Venue

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Abstract

Pesticidal mixtures of triazines with other fungicides and pesticides are disclosed. Fungicidal compounds are often applied in conjunction with one or more other fungicides to control a wider variety of undesirable diseases and with other pesticides in order to control numerous pests within the same application. Typical pesticides include insecticides, nematocides, miticides, arthropodicides, bactericides or combinations thereof.

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Fungicidal Mixtures

Triazine derivatives, such as 4-(2-aminopyridin-4-yl)-N-phenyl-1,3,5-triazin-2-amine derivatives, are useful in fungicidal compositions and are typically described by the following formula:

wherein R1, R2, R3, R4, and R5 are each independently selected from H, alkyl, halogen, alkylhalo, alkoxy, alkoxyhalo or cyano; R6 and R7 are each independently selected from H, alkyl, cycloalkyl, alkenyl, alkylalkenyl, alkylalkynyl, aryl, alkylaryl, alkylhalo, alkoxy, alkylalkoxy, alkylalkoxyalkoxy, alkylalkoxyhalo, alkylhydroxy, alkylaryloxy,  or alkylamino, or when taken together R6 and R7 can form a saturated or unsaturated 5 or 6 membered ring selected from piperazine, piperidine, morpholine, thiomorpholine, pyrrolidine, oxazolidine, thiazolidine, tetrahydroisoquinoline, decahydroisoquinoline, pyrroline, and tetrahydropyridine, wherein the 5 or 6 membered ring can be additionally substituted with one or more alkyl, aryl, alkoxy, halo, and/or amino groups; and R8, R9, and R10 are each independently selected from hydrogen, alkyl, halogen, haloalkyl, and alkoxy, and R11 is selected from H, alkyl, alkenyl, alkylalkenyl, alkylalkynyl,  CH2OR12, CH2SR12, -C(O)R12, C(O)OR12, SO2R12, SOR12, or SR12, wherein R12 is selected from alkyl, alkylalkoxy, alkylhalo or alkylphenyl, wherein the phenyl may be substituted by up to 3 groups selected from halo or alkyl; and agronomically acceptable enantiomorphs, acid addition salts and metal complexes thereof.

Triazines can also be combined with other fungicides to form fungicidal mixtures and synergistic mixtures thereof.  Fungicidal compounds are often applied in conjunction with one or more other fungicides to control a wider variety of undesirable diseases. When used in conjunction with other fungicide(s), triazine compounds can be formulated with the other fungicide(s), tank mixed with the other fungicide(s) or applied sequentially with the other fungicide(s). Such other fungicides include enestrobin, antimycin, quinoxyfen, SYP-048, IK-1140, NC-224, 2-(thiocyanatomethylthio)-benzothiazole, 2-phenylphenol, 8-hydroxyquinoline sulfate, Ampelomyces quisqualis, azaconazole, azoxystrobin, Bacillus subtilis, benalaxyl, benomyl, benthiavalicarb-isopropyl, benzylaminobenzene-sulfonate (BABS) salt, bicarbonates, biphenyl, bismerthiazol, bitertanol, blasticidin-S, borax, Bordeaux mixture, boscalid, bromuconazole, bupirimate, calcium polysulfide, captafol, captan, carbendazim, carboxin, carpropamid, carvone, chinomethionate, chloroneb, chlorothalonil, chlozolinate, Coniothyrium minitans, copper hydroxide, copper octanoate, copper oxychloride, copper sulfate, copper sulfate (tribasic), cuprous oxide, cyazofamid, cyflufenamid, cymoxanil, cyproconazole, cyprodinil, dazomet, debacarb, diammonium ethylenebis-(dithiocarbamate), dichlofluanid, dichlorophen, diclocymet, diclomezine, dichloran, diethofencarb, difenoconazole, difenzoquat ion, diflumetorim, dimethomorph, dimoxystrobin, diniconazole,diniconazole-M,din...